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91.
92.
Northwest Africa (NWA) 4898 is the only low‐Ti, high‐Al basaltic lunar meteorite yet recognized. It predominantly consists of pyroxene (53.8 vol%) and plagioclase (38.6 vol%). Pyroxene has a wide range of compositions (En12–62Fs25–62Wo11–36), which display a continuous trend from Mg‐rich cores toward Ca‐rich mantles and then to Fe‐rich rims. Plagioclase has relatively restricted compositions (An87–96Or0–1Ab4–13), and was transformed to maskelynite. The REE zoning of all silicate minerals was not significantly modified by shock metamorphism and weathering. Relatively large (up to 1 mm) olivine phenocrysts have homogenous inner parts with Fo ~74 and sharply decrease to 64 within the thin out rims (~30 μm in width). Four types of inclusions with a variety of textures and modal mineralogy were identified in olivine phenocrysts. The contrasting morphologies of these inclusions and the chemical zoning of olivine phenocrysts suggest NWA 4898 underwent at least two stages of crystallization. The aluminous chromite in NWA 4898 reveals that its high alumina character was inherited from the parental magma, rather than by fractional crystallization. The mineral chemistry and major element compositions of NWA 4898 are different from those of 12038 and Luna 16 basalts, but resemble those of Apollo 14 high‐Al basalts. However, the trace element compositions demonstrate that NWA 4898 and Apollo 14 high‐Al basalts could not have been derived from the same mantle source. REE compositions of its parental magma indicate that NWA 4898 probably originated from a unique depleted mantle source that has not been sampled yet. Unlike Apollo 14 high‐Al basalts, which assimilated KREEPy materials during their formation, NWA 4898 could have formed by closed‐system fractional crystallization.  相似文献   
93.
Bulk major element composition, petrography, mineralogy, and oxygen isotope compositions of twenty Al‐rich chondrules (ARCs) from five CV3 chondrites (Northwest Africa [NWA] 989, NWA 2086, NWA 2140, NWA 2697, NWA 3118) and the Ningqiang carbonaceous chondrite were studied and compared with those of ferromagnesian chondrules and refractory inclusions. Most ARCs are marginally Al‐richer than ferromagnesian chondrules with bulk Al2O3 of 10–15 wt%. ARCs are texturally similar to ferromagnesian chondrules, composed primarily of olivine, pyroxene, plagioclase, spinel, Al‐rich glass, and metallic phases. Minerals in ARCs have intermediate compositions. Low‐Ca pyroxene (Fs0.6–8.8Wo0.7–9.3) has much higher Al2O3 and TiO2 contents (up to 12.5 and 2.3 wt%, respectively) than that in ferromagnesian chondrules. High‐Ca pyroxene (Fs0.3–2.0Wo33–54) contains less Al2O3 and TiO2 than that in Ca,Al‐rich inclusions (CAIs). Plagioclase (An77–99Ab1–23) is much more sodic than that in CAIs. Spinel is enriched in moderately volatile element Cr (up to 6.7 wt%) compared to that in CAIs. Al‐rich enstatite coexists with anorthite and spinel in a glass‐free chondrule, implying that the formation of Al‐enstatite was not due to kinetic reasons but is likely due to the high Al2O3/CaO ratio (7.4) of the bulk chondrule. Three ARCs contain relict CAIs. Oxygen isotope compositions of ARCs are also intermediate between those of ferromagnesian chondrules and CAIs. They vary from ?39.4‰ to 13.9‰ in δ18O and yield a best fit line (slope = 0.88) close to the carbonaceous chondrite anhydrous mineral (CCAM) line. Chondrules with 5–10 wt% bulk Al2O3 have a slightly more narrow range in δ18O (?32.5 to 5.9‰) along the CCAM line. Except for the ARCs with relict phases, however, most ARCs have oxygen isotope compositions (>?20‰ in δ18O) similar to those of typical ferromagnesian chondrules. ARCs are genetically related to both ferromagnesian chondrules and CAIs, but the relationship between ARCs and ferromagnesian chondrules is closer. Most ARCs were formed during flash heating and rapid cooling processes like normal chondrules, only from chemically evolved precursors. ARCs extremely enriched in Al and those with relict phases could have had a hybrid origin (Krot et al. 2002) which incorporated refractory inclusions as part of the precursors in addition to ferromagnesian materials. The occurrence of melilite in ARCs indicates that melilite‐rich CAIs might be present in the precursor materials of ARCs. The absence of melilite in most ARCs is possibly due to high‐temperature interactions between a chondrule melt and the solar nebula.  相似文献   
94.
通过对新疆柯坪地区中、上奥陶统萨尔干组和坎岭组高分辨率磁化率数据进行旋回地层学研究,识别出405kyr 长偏心率,111 kyr 短偏心率,38.6kyr、34.1 kyr 和31.0kyr 斜率,以及21.8kyr、20.2 kyr、18.5 kyr 和18.2 kyr岁差旋回,其中斜率信号突出.滤波结果显示萨尔干组和坎岭组记录了 13个405 kyr长偏心率沉积旋回.通过天文校准得出萨尔干组的沉积时限是~2.63 Myr,沉积速率为4.94 m/Myr;坎岭组的沉积时限是~2.64 Myr,沉积速率为5.30m/Myr.萨尔干组滞流盆地相页岩比坎岭组陆棚灰岩沉积速率低.研究层段的0.16-0.17 m沉积旋回信号明显,表明地轴斜率是研究区中、晚奥陶世重要的气候驱动因子.旋回地层学研究结果还赋予生物化石带地质时代意义,大湾沟剖面所产牙形石带Eoplacognathus suecicus、Pygodus serra、Pygodus anserinus、Baltoniodus variabilis 和 Baltoniodus alobatus 的综合延续时限大于5.27 Myr;所产笔石带 Pterograptus elegans、Glossograptus hincksii、Nemagraptus gracilis 和 Corynoides americanus 的综合延续时限为~5.27 Myr.  相似文献   
95.
刘国栋  付勇  何伟  唐波  龙珍  杨颖  龙克树 《地质论评》2021,67(3):67040003-67040003
钪(Sc)作为新世纪的重要资源,广泛分布于自然界中,但其分布极为稀散,钪的独立矿物稀少,独立矿床几乎没有。铝土岩系中的钪资源储量巨大,本文统计了中国各铝土矿成矿带Sc数据,在对比山西(断隆)成铝区、华北陆块南缘成铝区、渝南—黔北成铝带、黔中成铝区和滇东南—桂西成铝区的数据基础上,发现滇东南—桂西成铝区的Sc含量最高,含钪铝土岩系形成时代主要为石炭纪和二叠纪。通过对比分析A/S与钪的关系,在A/S小于2.5,钪的含量总体较高,且与A/S正相关,大于2.5后,与A/S负相关。从而得出在铝土岩系中,Sc分布在顶层的黏土岩、中部的铁质铝土矿以及底部的铁质黏土岩、铁质岩,尤其是在含铁铝土岩系中高度富集。通过对比分析铝土岩系各元素含量,发现钪与铁、铌、钒、铬元素成正相关,综合铝土岩系中其他元素的矿物表现形式,推测钪在铝土岩系中的赋存形式可能为:类质同象、离子吸附、和超显微非结构混入物。本文初步探讨总结钪在铝土岩系中可能的赋存形式、时空分布规律及钪的迁移转化机制,为铝土矿中伴生钪资源的综合利用开发提供理论支撑。  相似文献   
96.
多环芳烃(polycyclic aromatic hydrocarbons,PAHs)是广泛存在于大气中的一类毒害有机污染物.本研究采集了2018年冬、夏两季珠江三角洲9个地级市的气态和颗粒态(PM2.5)样品,分析了16种美国国家环境保护局优先控制PAHs的浓度水平和时空变化,并结合PM2.5相中的有机碳(OC)、元素碳(EC)和左旋葡聚糖浓度,使用正定矩阵因子分解(PMF)模型对PAHs进行了来源解析.∑16 PAHs的气相浓度范围为7.08~284.08 ng/m3,PM2.5相浓度范围为0.30~17.00 ng/m3,两相总浓度(37.48±41.53)ng/m3.季节特征上,∑16 PAHs气相浓度为夏高冬低,PM2.5相浓度则呈现冬高夏低,总∑16 PAHs浓度呈夏高冬低.比值法和PMF源解析结果发现,珠江三角洲9个典型城市大气的PAHs主要来自生物质燃烧(57%)、煤炭燃烧(30%)和机动车尾气排放(13%).城市周边生物质燃烧引致的PAHs污染仍需重视.健康风险评价表明,珠江三角洲大气PAHs致癌等效浓度处于较低水平(0.30~1.89 ng/m3),主要由苯并[a]芘贡献(>45%),建议重点关注.  相似文献   
97.
Geotechnical and Geological Engineering - In order to analyze the characteristics of the mechanical property, failure mode and acoustic emission of the columnar jointed rock masses,...  相似文献   
98.
Feng  Boyu  Zhang  Ying  Bourke  Robin 《Natural Hazards》2021,106(1):613-627
Natural Hazards - Urbanization increases regional impervious surface area, which generally reduces hydrologic response time and therefore increases flood risk. The objective of this work is to...  相似文献   
99.
任磊  朱颖  崔天麟 《地球科学》2021,46(6):2278-2286
郑州地铁某盾构区间超近距离侧穿铁路桥梁桩基,受地面空间及隧道与桥桩间净距限制,无法采用隔离桩等常规保护措施.结合工程实际情况提出“盾构通过范围内土体注浆加固”、“桥梁承台加固”以及“注浆+承台加固”三种措施,利用数值模拟手段,对盾构侧穿施工期间,不同保护方案下桥桩的变形规律进行了分析研究.研究结果表明,采用“盾构通过范围内土体注浆加固+承台加固”措施,可使桥面最大沉降值减少约45%,且可减少桥面横桥向不均匀沉降及桥桩水平位移,在很大程度上减少盾构隧道施工对铁路桥梁的不利影响.   相似文献   
100.
多宝山矿区发现有侵位于晚奥陶世花岗闪长岩的角闪辉长岩和英云闪长岩,二者具有双峰式侵入岩的特征,在详细的野外地质调查基础上,对多宝山双峰式侵入岩进行了岩石学、年代学、地球化学方面的研究,并初步探讨其构造意义.角闪辉长岩的LA-ICP-MS锆石U-Pb年龄为224.3±1.7 Ma,英云闪长岩为226.3±2.3 Ma,两者形成于同一构造岩浆作用事件;侵入岩的SiO2含量呈双峰式,稀土、微量元素特征表明它们具有岛弧岩浆特征,二者具有相同的岩石圈地幔源区,其源区可能受到了俯冲流体交代作用的影响.结合区域构造背景,认为其形成与鄂霍茨克洋壳俯冲有关,产于活动大陆边缘环境,它们可能是受地壳混染的OIB型玄武质岩浆在地壳中部的一个“双扩散”岩浆房通过结晶分异形成的.   相似文献   
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